Rendement
Rendement
is actually a term in the field of chemistry studies. The yield represents the
inaccuracy of the reaction result, which results always lower than the
mathematical calculation. For example, in a chemical reaction, should produce a
substance weighing 100 grams, mathematically, but in reality the results
obtained only 90 grams. Unconsciously this also often happens in our daily
lives loh.
In a chemical reaction we can always calculate the reaction results as much as 100%, but in reality it never happened in practice.
In a chemical reaction we can always calculate the reaction results as much as 100%, but in reality it never happened in practice.
Chemistry is:
Section of natural science, studying the
elements that make up all the substances / compounds that exist, that includes
the structure, how the elements combine to form other substances / compounds,
and how the reaction to different conditions.
Physical and Chemical Properties:
To know the properties of a compound, we
need to know its physical properties, which can be observed without altering
its identity, and chemical properties, which can be shown only through chemical
changes.
Measurements and Units:
Chemistry is a quantitative science and
requires measurement. Measurable quantities (such as mass, volume, density, and
temperature) typically have their respective units. The units used in chemistry
are based on international system units (SI).
Handling Numbers:
Scientific notation is used to denote
small numbers and large numbers, and each number in a measurement must show,
the number of digits is called a meaningful number
Graph:
Graphics are used to help organize the
information, because it provides a visual representation of a topic, clearly
showing how important concepts are linked.
Chemical calculation:
A simple and effective way to perform
chemical calculations is the conversion factor method, which is based on
dimensional analysis.
DIAGRAM A GENERAL WAY TO FULLY
PROBLEM STOIKIOMETRY INVOLVING A CHEMICAL REACTION
GRAM
ZAT A ® MOL ZAT A ® MOL
ZAT B ® GRAM ZAT B
1
mol A / g A of the mol ratio B
x Gr B / mol
(X
1 / molar mass) mole coefficient A (x molar mass B)
To mol B
Evaluation Of Success Reaction
Theoretical Rendemen A Particular
Product Is
The
maximum result obtained if the reactants only produce the product without side
reactions
REAL RENDEMEN
is the number of products actually gained in an experiment
In
chemistry, the chemical yield, the yield of the reaction, or only the rendement
refers to the amount of reaction product produced in the chemical reaction. [1]
Absolute rendement can be written as weight in grams or in moles (molar yield).
The relative yield used as a calculation of the effectiveness of the procedure
is calculated by dividing the amount of product obtained in moles by the
theoretical yield in moles:
To
obtain a percentage yield, multiply the fractional yield by 100%.
One
or more reactants in chemical reactions are often used redundantly. The
theoretical rendement is calculated based on the number of moles of the
limiting reagent. For this calculation, it is usually assumed there is only one
reaction involved.
The
ideal chemical yield value (theoretical rendement) is 100%, a value highly
unlikely to be achieved in its practice. Calculate the percentage of rendement
that is by using the following equation percent rendemen = weight yield /
weight of yield divided by the sample weight multiplied 100%.
Chemical Reactions
a. Burning Reactions
Is
a reaction between a substance with oxygen to produce substances that are new
and hot. Combustion reactions may also cause fire, explosion, or only cause fl
uor.
Fuel
combustion generally generates carbon dioxide gas, water vapor and some energy.
Examples such as fuel combustion in a motor vehicle.Pentanes are burned to
produce carbon dioxide gas and water vapor
B.
Combination Reactions
Combination
reactions are often referred to as oxidation-reduction reactions or redox reactions
which are free elements.In the oxidation reaction can be found when two or more
reactants become new substances. An example of a coupling reaction is for
example the reaction between iron with sulfur (sulfur) which produces iron
sulphide and zinc compounds with sulfur heated to zinc sulphide.
Oxidation reaction
also takes place in the process of respiration that is the process of oxidation
of glucose in the body of living things.
Reduction reaction
occurs when a substance loses oxygen. This reaction is usually used to extract
metals from the ore.
c. Decomposition Reactions
In
the decomposition reaction that occurs is the opposite of the merging reaction.
Where a substance decomposes into two or more new substances. Examples of
decomposition reactions eg in the process of electrolysis water into hydrogen
gas and oxygen gas using electricity, the reaction is as follows:
d. Replacement Reactions
Reaction
reactions can be divided into two kinds: single replacement reactions and
multiple replacement reactions.
1. A single replacement reaction occurs
when an element replaces the position of another element in a chemical reaction,
For example in the reaction between the copper wire dipped in the silver
nitrate solution. Since copper is more active than silver, copper replaces the
silver position to form a blue copper (II) nitrate solution.
2. Double replacement reactions
can occur in ionic interchange of atoms or compounds such as in the reaction
process between hydrochloric acid (HCl) and sodium hydroxide (NaOH) to produce
the salt of the kitchen (NaCl) and water (H2O).
e. Metathesis reaction,
consisting
of:
• depositional reaction; A reaction
process that forms a precipitate, as in the reaction between lead (II) nitrate
and potassium iodide yields a yellow sized lead (II) iodide and a solution of
potassium nitrate
• neutralization reaction; Is a
reaction between acids and bases that produce salt and water
• gas formation reaction; Is a chemical
reaction in the gas produced product
• in the fermentation process involving
microorganisms, ie yeast. In baking, yeast added to the dough will cause the
bread dough to expand. Because carbon dioxide is formed when baking soda
(NaHCO3) is added to the dough and the roasting process causes the yeast cells
to die, the fermentation process stops.
• ferrous metals can react quickly with
hydrochloric acid (HCl) to form iron (II) chloride (FeCl2) and hydrogen gas
(H2)
Example Problem-1:
A
reaction takes place according to the following reaction equation:
2Al
+ 3Cl2 → 2AlCl3
a.
Available 1.2 mol of Al and 2.4 mol of Cl2 what substance acts as a limiting
reagent and what is the residual unreacted substance based on the equation of
the reaction?
b.
Available 1.2 grams Al and 2.4 grams of Cl2, what substance acts as a limiting
reagent and what is the residual unreacted substance based on the equation of
the reaction?
Solving
Problem-1a.
If
the data is given in units of moles for each substance, it can be used directly
to determine which limiting reagent and how much of the unused substance in the
reaction. Based on the equation of the reaction which has equalized the number
of elements on the left and right of the arrow then the ratio of the number of
moles of Al and Cl2 reagents is 2: 3. Remember that the mole ratio will be
proportional to the ratio of the equivalent coefficient of each substance. Check
the mole ratio with the coefficients of each reactant:
2Al
→ 1.2 mol ÷ 2 = 0.6 mol
3Cl2
→ 2.4 mol ÷ 3 = 0.8 mol
The
smallest comparison ratio (Al = 0.6 mol) will be exhausted first and Al is the
limiting reagent.
Cl2
reacted = 0.6 mol × 3 (3 → coefficient Cl2) = 1.8 mol.
Cl2
that does not run out = 2.4 mol - 1.8 mol = 0.6 mol.
Solving
Problem-1b:
Since
the data presented in grams can not be solved directly, it is necessary to
convert grams to moles first.
1.2
g Al = 1.2 g ÷ 27 g / mol = 0.044 mol Al
2.4
g Cl2 = 2.4 g ÷ 71 g / mol = 0.033 mol Cl2
Check
the mole ratio with the coefficients of each reactant:
2Al
→ 0.044 mol ÷ 2 = 0.022 mol
3Cl2
→ 0.033 mol ÷ 3 = 0.011 mol
The
smallest comparison ratio (Cl2 = 0.011 mol) will be exhausted first and Cl2 is
the limiting reagent.
The
exhausted Al = 0.011 mol x 2 (2 → Al coefficient) = 0.022 mol.
The
unreacted Al = 0.044 mol - 0.022 mol = 0.022 mol Al
0.022
mol Al = 0.022 mol × 27 g / mol = 0.594 g
How the rendement of the reduction and oxidation reactions ?
BalasHapus1. The binding and release of the oxygen element
HapusThe oxidation reaction (oxygenation) is the event of combining a substance with oxygen.
Example:
Si + O2 â +'SiO2
4 Fe + 3 O2 â + '2 Fe2O3
The oxidation reaction of the metal is also known as the name of the carnation. Combustion reactions also include oxidation reactions, such as petroleum burning, paper, firewood, etc.
The reduction reaction is an oxygen discharge event of a substance.
Example:
2 CuO â + '2 Cu + O2
H2O â +'H2 + O2
2. Electron release and binding reaction
The oxidation and reduction reactions can also be distinguished from the release and capture of electrons.
Oxidation is an electron release event
Example:
Na â + 'Na + + e
Zn - Zn + 2 + 2e
Al '+' Al + 3 + 3e
Reduction is an electron capture event
Example:
Na + + e â + 'Na
Fe +3 + e â +'Fe +2
From this second concept it can be concluded that oxidation and reduction reactions involve not only the reaction of a substance with oxygen.
Similarly, the ordinary reaction percentage of the yield obtained from the amount of substance produced divided by the theoretical results
What is the difference between real yield and theoretical rendement?
BalasHapusThe real result is the measured result directly using the measuring device.
HapusWhile the results of measurement theory based on theories of theory that already exist without measuring directly
Why ferrous metals can react quickly with hydrochloric acid (HCl) ?
BalasHapusIt readily reacts with nonmetallic elements such as halogens, sulfur, pospor, boron, carbon and silicon. Soluble in dilute mineral acids. The oxide is amphoteric.
HapusSo the iron can react with hydrochloric acid
Why are reactants in chemical reactions often overused?
BalasHapusThis is because the ratio of reactants that will react to form a new compound is not always 1 to 1 so that there will always be residual in one of the reactants that does not run out, the determination of the reactant that has been reacted can be done by using a limiting reaction.
HapusWhat is the conclusion about your article?
BalasHapusThe conclusion of this article is that the yield of a chemical reaction is not one hundred percent fit because the reality difference is not always the same with the results obtained in theory other than that in a reaction kimi reaktan also not always exhausted, usually that is merupakn limiting reaction.
HapusWhat is the difference of a single replacement reaction with a double replacement reaction?
BalasHapusReaction reactions can be divided into two kinds: single replacement reactions and multiple replacement reactions.
Hapus1. A single replacement reaction occurs when an element replaces the position of another element in a chemical reaction
For example in the reaction between the copper wire dipped in the silver nitrate solution. Since copper is more active than silver, copper replaces the silver position to form a blue copper (II) nitrate solution.
2. Double replacement reactions can occur in ionic interchange of atoms or compounds such as in the reaction process between hydrochloric acid (HCl) and sodium hydroxide (NaOH) to produce the salt of the kitchen (NaCl) and water (H2O).
If we mix H2SO4 with cold air, what will be different percentage of its rendement prediction when compared to mixing H2SO4 with water in a hole?
BalasHapusAsam sulfat murni yang tidak diencerkan tidak dapat ditemukan secara alami di bumi oleh karena sifatnya yang higroskopis. Walaupun demikian, asam sulfat merupakan komponen utama hujan asam, yang terjadi karena oksidasi sulfur dioksida di atmosfer dengan keberadaan air (oksidasi asam sulfit). Sulfur dioksida adalah produk sampingan utama dari pembakaran bahan bakar seperti batu bara dan minyak yang mengandung sulfur (belerang).
HapusAsam sulfat terbentuk secara alami melalui oksidasi mineral sulfida, misalnya besi sulfida. Air yang dihasilkan dari oksidasi ini sangat asam dan disebut sebagai air asam tambang. Air asam ini mampu melarutkan logam-logam yang ada dalam bijih sulfida, yang akan menghasilkan uap berwarna cerah yang beracun. Oksidasi besi sulfida pirit oleh oksigen molekuler menghasilkan besi(II), atau Fe2+: