CHEMICAL VOCABULARY
NO
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VOCABULARY
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EXPLANATION
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1
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acid
dissociation constant (Ka)
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This
is equal to the ratio of the concentrations of an acid's conjugate base and
the acid present when a weak acid dissociates in water. That is, if you have
a solution of Acid X where the concentration of the conjugate base is 0.5 M
and the concentration of the acid is 10 M, the acid dissociation constant is
0.5/10 = 0.05.
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2
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activation energy
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The minimum
amount of energy needed for a chemical reaction to take place. For some
reactions this is very small (it onl takes a spark to make gasoline burn).
For others, it's very high (when you burnmagnesium, you need to hold it over
a Bunsen burner for a minute or so).
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3
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Avogadro's Law
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If
you've got two gases under the same conditions of temperature, pressure, and
volume, they've got the same number of particles (atoms or molecules). This
law only works for ideal gases, none of whichactually exist.
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4
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calorimetry
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The study of
heat flow. Usually you'd do calorimetry to find the heat of combustion of a
compound or the heat of reaction of two compounds.
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5
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chromatography
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This is when you use a system
containing a mobile phase (usually a liquid in general chemistry classes) and
a stationary phase (something dissolved in the liquid) to separate different
compounds. This is usually done by exploiting the differing polarities of
solutes, though you can do it a whole slew o' ways.
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6
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circuit
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The closed
path in a circuit through which electrons flow.
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7
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coagulation
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When
you destroy a colloid by letting the particles settle out.
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8
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decomposition: When a big
molecule falls apart to make two or more little ones.
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9
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degenerate
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Things
(usually orbitals) are said to be degenerate if they have the same energy.
This term is used a whole lot in quantum mechanics. Also when dealing with
kids who steal cars.
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10
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delocalization
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This is when
electrons can move around all over a molecule. This happens when you have
double bonds on adjacent atoms in a molecul(conjugated hydrocarbon)
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11
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endothermic
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When a process absorbs energy (gets
cold).
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12
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functional group
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A
generic term for a group of atoms that cause a molecule to react in a
specific way. It's really common to talk about this in organic chemistry,
where you have "aldehydes, carboxylic acids, amines" and so on.
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13
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gamma ray
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High energy light given off during a nuclear
process. When a nucleus gives off this light, it goes to a lower energy
state, making it mor stable.
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14
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geometrical isomer:
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isomerism
where atoms or groups of atoms can take up
different positions around a double bond or a ring. This is also called
cistrans-isomerism.
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15
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heterogeneous
mixture
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A mixture where the substances aren't
equally
distributed.
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16
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homogeneous mixture:
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A
mixture that looks really "smooth" because
everything is
mixed up really well.
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17
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irreversible
reaction
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A
chemical reaction in which the reagents make products but the products can't
reform reagents. Most chemical reactions in basic chemistry classes are
thought of as being irreversible.
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18
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isotonic solutions
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Solutions
containing the same osmotic pressure
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19
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Lewis acid
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An electron-pair
acceptor (carbonyl groups are really good ones)
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20
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Lewis base:
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An
electron-pair donor. Things with lone pairs like water and ammonia are really
good ones.
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21
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Lewis
structure
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A
structural formula that shows all of the atoms and valenceelectrons in a
molecule.
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22
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ligand
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A molecule or
ion that sticks to the central atom in a complex.
Common examples are ammonia, carbon
monoxide, or water.
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23
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limiting
reagent
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If
you do a chemical reaction and one of the chemicals gets used up before the
other one, the one that got used up is called the "limiting reagent"
because it limited the amount of product that could be formed. The other one is called the excess reagent.
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24
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line spectrum
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A spectrum
showing only certain wavelengths.
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25
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mechanism
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A
step-by-step sequence that shows how the products of a reaction are made from
the reagents. Mechanisms are very frequently shown during organic chemistry.
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26
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molality
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The
number of moles of solute per kilogram of solvent in a solution. This is a
unit of concentration that's not anywhere near as handy or common as
molarity.
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27
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molar mass:
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The
mass of one mole of particles.
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28
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molar volume:
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The volume of
one mole of a substance at STP. If you believe that everything is an ideal
gas, this is always 22.4 liters. Unfortunately,there's no such thing as an
ideal gas.
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29
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molecular
compound
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A compound held together by covalent
bonds.
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30
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molecular formula
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A formula that
shows the correct quantity of all of the atoms in a molecule.
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31
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monatomic ion
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An
ion that has only one atom, like the chloride ion.
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32
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optical isomerism
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Isomerism in
which the isomers cause plane polarized light to rotate in different
directions.
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33
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orbital
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This
is where the electrons in an atom live.
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34
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organic compound
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A compound
that contains carbon (except carbondioxide, carbon monoxide, and carbonates)
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35
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osmosis
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The
flow of a pure liquid into an area of high concentration through
a
semi-permeable membrane
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36
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oxidation number
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The apparent
charge on an atom.
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37
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STP
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See
standard temperature and pressure.
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38
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unshared electron pair:
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two electrons
that aren't involved in chemical
bonding.
Also frequently referred to as a "lone pair".
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39
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unshared
electron pair
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two
electrons that aren't involved in chemical
bonding. Also frequently referred to as a "lone pair".
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40
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valence electron
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The outermost
electrons in an atom.
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41
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synthesis
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When
you make a big molecule from two or more smaller ones.
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42
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system
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Everything
you're talking about at the moment.
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43
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temperture:
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A
measurement of the average kinetic energy of the particles in a system
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